Bewitched

Season 4 Episode 18:

Once in a Vial

Endora hires Rollo to get Samantha away from Darrin, but her plan backfires when Rollo creates a love potion for Samantha but Endora drinks it instead. Endora is set to marry a client of Darrin's, but at the altar, the potion wears off.
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About Bewitched:

Samantha Stephens is a seemingly normal suburban housewife who also happens to be a genuine witch, with all the requisite magical powers. Her husband Darrin insists that Samantha keep her witchcraft under wraps, but situations invariably require her to indulge her powers while keeping her bothersome mother Endora at bay.