The Twilight Zone (’59–’64)

Season 1 Episode 31:

The Chaser

A young man obsessed with winning over an uninterested beauty gets more than he bargained for when he buys a love potion to gain her affection.
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About The Twilight Zone (’59–’64):

Rod Serling's seminal anthology series focused on ordinary folks who suddenly found themselves in extraordinary, usually supernatural, situations. The stories would typically end with an ironic twist that would see the guilty punished.