Season 6 Episode 6:
When Red is sent to a federal medical institution following his request to the court for a psychiatric evaluation, Liz and Jennifer use his time away to search for a Blacklister they believe may have valuable information about Red's past.
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About The Blacklist:
Raymond "Red" Reddington, one of the FBI's most wanted fugitives, surrenders in person at FBI Headquarters in Washington, D.C. He claims that he and the FBI have the same interests: bringing down dangerous criminals and terrorists. In the last two decades, he's made a list of criminals and terrorists that matter the most but the FBI cannot find because it does not know they exist. Reddington calls this "The Blacklist". Reddington will co-operate, but insists that he will speak only to Elizabeth Keen, a rookie FBI profiler.