Season 6 Episode 7:

Family Matters

Dean suspects Samuel and he joins his team with Sam to hunt the vampire Alpha. Dean sneaks out and sees Samuel capturing the Alpha and taking him in a van for interrogation. Sam plants a GPS in Samuel's car to follow him with Dean and they discover that their grandfather wants to find out where purgatory is. The Alpha escapes and subdues Sam, but Dean vanquishes the Alpha injecting dead man blood in him. Out of the blue, Crowley appears and tells that he had brought Sam and Samuel back from Hell since he is powerful now. Further, Christian is a demon and Samuel is ...
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About Supernatural:

Two brothers follow their father's footsteps as "hunters" fighting evil supernatural beings of many kinds including monsters, demons, and gods that roam the earth.