Supernatural

Season 3 Episode 1:

The Magnificent Seven

Sam, Dean, and Bobby deal with the ramifications of the Gate to Hell opening, meeting the demon incarnations of the Seven Deadly Sins, while Dean is living life to the fullest in the shadow of a deal he made with the Crossroads Demon, and a mysterious blonde woman with a demon-killing knife assists Sam.
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About Supernatural:

Two brothers follow their father's footsteps as "hunters" fighting evil supernatural beings of many kinds including monsters, demons, and gods that roam the earth.