Gossip Girl

Season 2 Episode 4:

The Ex-Files

When Dan starts getting cozy with Amanda, the new girl at school, Serena turns to Blair and her minions to step in to sabotage her chances. Vanessa also enlists Blair's help when she finds out a scandalous secret about Catherine.
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About Gossip Girl:

Privileged teens living on the Upper Eastside of New York City.