The Flintstones

Season 5 Episode 8:

Dr. Sinister

Fred and Barney are caught up in a swirl of spies' intrigue, with exotic and menacing strangers and multiple threats on their lives, all while Wilma and Betty are waiting for them to return with the burgers and buns.
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About The Flintstones:

The misadventures of a modern stone-age family and friends.