Season 1 Episode 3:

Hedge Fund Homeboys

A clique of rich kids plays Russian Roulette with a bullet-less gun. But one night a bullet in the chamber kills one of them. When another one is supposedly commits suicide it's up to the team to discover what is what and if the suicide was over guilt.
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About Castle:

After a serial killer imitates the plots of his novels, successful mystery novelist Richard "Rick" Castle gets permission from the Mayor of New York City to tag along with an NYPD homicide investigation team for research purposes.