Avatar: The Last Airbender

Season 3 Episode 14:

The Boiling Rock: Part 1

Sokka and Zuko infiltrate the ultimate Fire Nation prison, the Boiling Rock. With hopes of freeing his father and his girlfriend, Sokka hatches an escape plan to get them all out.
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About Avatar: The Last Airbender:

In a war-torn world of elemental magic, a young boy reawakens to undertake a dangerous mystic quest to fulfill his destiny as the Avatar.