Season 1 Episode 86:

Bubba Bo Bob Brain

The Brain becomes a country-western star in order to plant hypnotic suggestions for world domination. But his main problem in his rise to fame: Pinky keeps screwing up his name.
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About Animaniacs:

The two Warner Brothers Yakko and Wakko and their Warner sister Dot had been (supposedly) created in the 1930's, but their cartoons were too screwy for the general public to handle. The three Warners were locked up in the studio water tower until they escaped in the 90's. There, they run wild, causing chaos everywhere!

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