Smallville

Season 10 Episode 14:

Masquerade

Chloe and Oliver are mistaken for FBI agents investigating Desaad's recent string of murders and the pair are kidnapped by Desaad's minions. Desaad tries to infect Chloe with the darkness. Meanwhile, Lois tells Clark he needs to be more careful with his identity and suggests a disguise.
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About Smallville:

The origins of the world’s greatest hero–from Krypton refugee Kal-el’s arrival on Earth through his tumultuous teen years to Clark Kent’s final steps toward embracing his destiny as the Man of Steel.


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